南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪   总被引：1，自引：1，他引：0  

张美  陆红锋  管红香  刘丽华  邬黛黛  吴能友 《海洋学报(英文版)》2018,37(7):20-27

The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage.  相似文献   

CARBON DYNAMICS OF WETLAND IN THE SANJIANG PLAIN   总被引：2，自引：0，他引：2  

SONG Chang-chun    WANG Yi-yong  WANG Yue-si  YAN Bai-xing WANG De-xuan  ZHAO Zhi-chun  LOU Yan-jing 《中国地理科学(英文版)》2003,13(3):228-231

1INTRODUCTIONWetlandsplayanimportant roleintheprocessofcar-bonstorage.Thetotalcarbonstoredindifferentkindsofwetlandsisabout15%-35%ofthetotalcarboninthegloballandsoils(POSTetal.,1982;GORHAM,1991).Inaddition,wetlandsaresignificantnaturalsources fortheatmospheric CH4 (MOORE,1994).It isestimatedthatabout110×1012gCH4 originates fromanaerobicdecompositioninthenaturalwetlands,CH4 emission fromthenaturalwetlandsis15%-30%oftheglobalCH4 emission andtheCH4 emission from thepeat land at hi…  相似文献   

Simulating methane emission from a Chinese rice field as influenced by fertilizer and water level     

Z. Yu  X. Shangguan  D. Pollard  E. J. Barron 《水文研究》2003,17(17):3485-3501

Natural and agricultural wetlands are considered to be the major sources of global atmospheric methane (CH₄). A one‐dimensional model was developed to simulate methane emission and used to examine the influence of various physical processes on the rate of methane emission. Three processes involved in the methane emission are implemented in the model: production, reoxidation and transport. Three transport pathways were considered: diffusion across water–air or soil–air interfaces, ebullition and diffusion through plants. These pathways are influenced by soil properties, plant growth, water‐table conditions, temperature and external inputs (e.g. fertilizer). The model was used to examine the seasonal variation of the methane emission at a rice field in Hunan, China, which was observed during a field experiment for consecutive (early and late) rice seasons in 1992. The observed seasonal variations of methane emission, and role of plants in transporting methane to the atmosphere, are captured by the model simulation. Further model applications were conducted to simulate effects of fertilizer and water‐level condition on the methane emission. The results indicate that unfermented organic fertilizer produces a higher methane emission rate than mineral fertilizer. The simulations with treatments of a deep‐water covering and constant moisture reduced the methane emission. The rice field study provides a framework for further development of the model towards simulations based on spatially distributed variables (e.g. water table, soil temperature and vegetation) at a regional scale. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Methane‐related microbial gypsum calcitization in stromatolites of a marine evaporative setting (Münder Formation,Upper Jurassic,Hils Syncline,north Germany)     

GERNOT ARP  CHRISTIAN OSTERTAG‐HENNING  SELÇÜK YÜCEKENT  JOACHIM REITNER  VOLKER THIEL 《Sedimentology》2008,55(5):1227-1251

Fossil stromatolites may reveal information about their hydrochemical palaeoenvironment, provided that assignment to a specific microbial community and a corresponding biogeochemical mechanism of formation can be made. Tithonian stromatolites of the Münder Formation at Thüste, north Germany, have traditionally been considered as formed by intertidal cyanobacterial communities. However, thin sections of the stromatolites show elongated angular traces of former gypsum crystals in a dense arrangement, but no algal or cyanobacterial filament traces. Moreover, high Fe²⁺ and Mn²⁺ contents, oxygen‐isotope and sulphur‐isotope ratios of carbonate‐bound sulphates, and sulphurized hydrocarbon biomarkers of the stromatolitic carbonate indicate that CaCO₃ precipitation occurred near the oxic–anoxic interface as a result of intensive bacterial sulphur cycling rather than photosynthetic activity. Furthermore, anaerobic oxidation of methane by Archaea may have driven CaCO₃ precipitation in deeper parts of the biofilm community, as reflected by high concentrations of squalane with a strongly negative δ¹³C in conjunction with evaporite pseudomorphs showing extremely low δ¹³C_Carb ratios. Consequently, the Thüste stromatolites are now interpreted as having initially formed by gypsum impregnation of biofilms. Subsequently, early Mg‐calcitic calcitization within the biofilms occurred because of combined bacterial iron, manganese and sulphate reduction, with an increasing contribution of anaerobic oxidation of methane with depth. This model plausibly explains the prominent preservation of signals derived from oxygen‐independent metabolic pathways, whereas virtually no geochemical record exists for an aerobic community that may, nevertheless, have prevailed at the stromatolite surface. Photic‐zone stromatolites with a prominent signal of anaerobic oxidation of methane may be common in, and indicative of, oxygen‐depleted sulphate‐bearing environments with high rates of methane production, conditions that possibly were fulfilled at the Archaean to Proterozoic transition.  相似文献   

高、低煤阶煤层气藏地质特征及控气作用差异性研究   总被引：4，自引：0，他引：4  

王勃  巢海燕  郑贵强  李景明  郭志斌  王红岩  刘洪林  李贵中 《地质学报》2008,82(10):1396-1401

高、低煤阶煤层气地质特征及控气作用差异性是研究煤层气富集成藏的重要组成部分,是煤层气勘探开发理论研究过程中重要的基础性研究领域之一。本文以中国沁水、阜新盆地和美国粉河盆地等典型的含气盆地为例,探讨了高、低煤阶煤层气的储层物性差异,分析了构造控气和水文地质控气作用的差异性。研究表明,高煤阶气藏含气量高,CH4百分含量高,δ13C1值大于-38.75‰,储层渗透率变化小,储层改造难,构造热事件对煤层气的生成、富集贡献大,持续的水动力使气藏遭到破坏,且破坏幅度大,现今地下水格局对气藏的形成具有一定的影响;低煤阶气藏含气量低,CH4百分含量低,δ13C1值大于-49.11‰,储层渗透率变化大,储层易改造,煤热演化史及煤阶影响着煤层气的生成、富集,在煤层气生成过程中活跃的水动力是甲烷生成的主要的水文地质条件之一,但持续的水动力使气藏遭到破坏,且破坏幅度小,而合适的地层水矿化度则是低煤阶煤层气生成的重要条件,地下水格局对气藏的调整和改造起到决定性的影响。  相似文献   

超低频电磁探测信号能量的计算及其地质应用   总被引：1，自引：0，他引：1  

宋本钦李培军  秦其明侯贵廷 《中国地质》2008,35(6):1315-1321

被动式超低频电磁探测技术是一种有效的探测地下地质体和资源的手段,但采用现有的处理方法得到的探测曲线较容易受到各种噪声的干扰,影响了对所获得的探测曲线的解释。笔者将信号能量引入到超低频电磁探测信号的处理中。首先根据信号能量计算原理,计算不同深度的超低频探测信号的能量值．获取能量曲线。同时,根据具体应用目的,分析其曲线特征,并将信号能量曲线与现有的信号曲线,如最大值曲线、最小值曲线等进行对比分析。结果表明,与现有方法相比,笔者所提出的信号能量曲线方法能更准确地反映地下岩层特征,有利于曲线的地质解译。  相似文献   

蒙特卡罗法在天然气水合物资源量计算中的应用     

曾繁彩  吴琳  张光学  梁金强  王宏斌 《海洋地质与第四纪地质》2006,26(5):139-144

天然气水合物甲烷资源量的估算是天然气水合物研究中的热点问题。运用体积法计算含水合物沉积物中的甲烷资源量时,存在参数赋值不确定的问题,从而影响了计算结果的可信度。采用蒙特卡罗法,通过计算样本的频率可以较好地评价和描述计算结果的信度,弥补体积法的不足。对采用蒙特卡罗法估算甲烷资源量的原理进行了分析和探讨,并以麦肯齐三角洲和南海海域水合物为例,计算了水合物赋存区的甲烷资源量。  相似文献   

GIS支持下的煤层气目标区模糊综合评价模型   总被引：4，自引：1，他引：3  

李贵中  白建梅  习铁宏  刘洪林  王德建  王勃 《现代地质》2008,22(1):103-106

地理信息系统(GIS)以空间数据库技术为核心,将空间要素与统计数据有机地结合在一起,具有直观灵活、分析功能强大、制表制图方便等优点。根据中国煤层气(CBM)目标区的特点,建立了4种原则下用于不同情形的煤层气目标区评价模型:第1种模型为全面考虑各个因素原则,第2种模型为只考虑重点因素原则,第3种模型为着重考虑重点因素原则,第4种模型为既全面考虑又兼顾重点因素原则。根据这4种模型,在常用GIS软件MapGIS基础上进行了二次开发并实现模型,以华北聚气区煤层气为例进行综合评价,目标区评价结果与实际情况基本相符。  相似文献   

华北地台中元古代碳酸盐岩中的微生物成因构造及其生烃潜力   总被引：6，自引：3，他引：3  

史晓颖  张传恒  蒋干清  刘娟  王议  刘典波 《现代地质》2008,22(5)

华北地台中元古界主要由环潮坪石英砂岩、浅海碳酸盐岩和浅海—泻湖相暗色页岩3种沉积相组合构成,以陆表海浅水碳酸盐岩占主导。碳酸盐岩中除含有丰富的微古植物、宏观藻类和微生物建隆外,还发育大量的微生物成因构造(MISS)和微生物诱发的碳酸盐沉淀(MMCP)。微生物席和MISS构造在高于庄组上部(约1.6 Ga)和雾迷山组下部(约1.45 Ga)碳酸盐岩中尤为发育,表明活跃的微生物活动和高有机质产量。在石化微生物席中,发现有丝状、球状细菌化石和草莓状黄铁矿;围岩中发现有针状文石、花瓣状重晶石、放射状菱铁矿、铁白云石和葡萄状碳酸盐胶结物等多种自生碳酸盐矿物,指示甲烷厌氧氧化(AOM)导致的自生碳酸盐沉淀。中元古代的温暖气候和海洋分层、缺氧、硫化条件有利于微生物的高生产量和高有机质埋藏率。气隆构造和核形石状碳酸盐结核反映浅埋藏条件下活跃的成烷作用和甲烷排放,围岩和MMCP中富沥青质。华北地台中元古界富微生物席碳酸盐岩有良好的生烃潜力,有可能形成重要的烃源岩。据微生物席、MISS构造及MMCP的研究,初步估算华北地台中元古代碳酸盐岩的概略生烃潜力约为10×108t石油当量。  相似文献   

华北安鹤煤田煤储层特征与煤层气有利区分布   总被引：3，自引：2，他引：1  

刘大锰  姚艳斌  刘志华  汤达祯  唐书恒  车遥  黄文辉 《现代地质》2008,22(5)

通过对安鹤煤田采集煤样的煤质、显微组分、煤相、显微裂隙分析,等温吸附、低温氮比表面及孔隙结构和压汞孔隙结构测试,研究了该区煤层气赋存的地质条件、煤层气生气地质特征和煤储层物性特征。并采用基于G IS的多层次模糊数学评价方法计算了该区的煤层气资源量,预测了煤层气有利区分布。研究结果表明,该区煤层气总资源量为1 115.73×108m3,煤层气资源丰度平均为1.18×108m3/km2,具有很好的煤层气资源开发潜力。在煤田中部的四矿到八矿之间的地区以及北部的水冶镇附近地区,煤层累计有效厚度大、煤层气资源丰度高、煤层埋深适中、煤储层孔裂隙系统发育、渗透性高,是该区煤层气勘探开发的最有利目标区。  相似文献